Photo-induced Charge-transfer and Photovoltaic Effect in a Composite Involving a Nonconjugated Conductive Polymer and C60
Identifieur interne : 003B24 ( Main/Repository ); précédent : 003B23; suivant : 003B25Photo-induced Charge-transfer and Photovoltaic Effect in a Composite Involving a Nonconjugated Conductive Polymer and C60
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Abstract
Photo-induced charge-transfer and resulting photovoltaic effect in a composite involving a nonconjugated conductive polymer, poly(β-pinene) and C60 is reported. The photovoltaic cell was fabricated using indium-tin-oxide coated glass as one electrode and aluminum as the other, with poly(β-pinene)-C60 composite film sandwiched in-between. A Nitrogen laser (325 nm) and an illuminant white-light-source (300-700 nm) were used and the photo-voltage produced was found to have a linear dependency on light intensity. The photoluminescence of poly(β-pinene) (at 360 nm) was quenched when C60 was added to form the composite. Therefore, the photovoltaic effect is a result of excited-state electron-transfer from poly(β-pinene) to C60.
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<front><div type="abstract" xml:lang="en">Photo-induced charge-transfer and resulting photovoltaic effect in a composite involving a nonconjugated conductive polymer, poly(β-pinene) and C<sub>60</sub>
is reported. The photovoltaic cell was fabricated using indium-tin-oxide coated glass as one electrode and aluminum as the other, with poly(β-pinene)-C<sub>60</sub>
composite film sandwiched in-between. A Nitrogen laser (325 nm) and an illuminant white-light-source (300-700 nm) were used and the photo-voltage produced was found to have a linear dependency on light intensity. The photoluminescence of poly(β-pinene) (at 360 nm) was quenched when C<sub>60</sub>
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